Atom
For other uses, see Atom (disambiguation).
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| An illustration of the helium atom, depicting the nucleus(pink) and the electron cloud distribution (black). The nucleus (upper right) in helium-4 is in reality spherically symmetric and closely resembles the electron cloud, although for more complicated nuclei this is not always the case. The black bar is one angstrom (10−10 m or100 pm). | ||||||||
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The atom is a basic unit of matter that consists of a dense centralnucleus surrounded by a cloud of negatively charged electrons. Theatomic nucleus contains a mix of positively charged protons and electrically neutral neutrons (except in the case of hydrogen-1, which is the only stable nuclide with no neutrons). The electrons of an atom are bound to the nucleus by the electromagnetic force. Likewise, a group of atoms can remain bound to each other by chemical bonds based on the same force, forming a molecule. An atom containing an equal number of protons and electrons is electrically neutral, otherwise it is positively or negatively charged and is known as an ion. An atom is classifiedaccording to the number of protons and neutrons in its nucleus: thenumber of protons determines the chemical element, and the number of neutrons determines the isotope of the element.[1]
Chemical atoms, which in science now carry the simple name of "atom," are minuscule objects with diameters of a few tenths of a nanometerand tiny masses proportional to the volume implied by these dimensions. Atoms can only be observed individually using special instruments such as the scanning tunneling microscope. Over 99.94% of an atom's mass is concentrated in the nucleus,[note 1] with protons and neutrons having roughly equal mass. Each element has at least one isotope with an unstable nucleus that can undergo radioactive decay. This can result in a transmutation that changes the number of protons or neutrons in a nucleus.[2] Electrons that are bound to atoms possess a set of stable energy levels, or orbitals, and can undergo transitions between them by absorbing or emitting photons that match the energy differences between the levels. The electrons determine the chemical properties of an element, and strongly influence an atom'smagnetic properties. The principles of quantum mechanics have been successfully used to model the observed properties of the atom.
Etymology
The name atom comes from the Greek ἄτομος (atomos, "indivisible") from ἀ- (a-, "not") and τέμνω (temnō, "I cut"),[3] which means uncuttable, or indivisible, something that cannot be divided further.[4]
History of atomic theory
Main article: Atomic theory
Atoms in philosophy
Main article: Atomism
The idea that matter is made up of discrete units is a very old one, appearing in many ancient cultures such as Greece and India. The word "atom", in fact, was coined by ancient Greek philosophers. However, these ideas were founded in philosophical and theological reasoning rather than evidence and experimentation. As a result, their views on what atoms look like and how they behave were very incorrect. They also couldn't convince everybody, so atomism was but one of a number of competing theories on the nature of matter. It wasn't until the 19th century that the idea was embraced and refined by scientists, when the blossoming science of chemistry produced discoveries that only the concept of atoms could explain.
First evidence-based theory
In the early 1800s, John Dalton used the concept of atoms to explain why elementsalways react in ratios of small whole numbers (the law of multiple proportions). For instance: there are two types of tin oxide—one is 88.1% tin and 11.9% oxygen and the other is 78.7% tin and 21.3% oxygen (tin(II) oxide and tin dioxide respectively). This means that 100g of tin will combine either with 13.5g or 27g of oxygen. 13.5 and 27 form a ratio of 1:2. This common pattern in chemistry suggested to Dalton that elements react in whole number multiples of discrete units—in other words, atoms. In the case of tin oxides, one tin atom will combine with either one or two oxygen atoms.[5]
Dalton also believed atomic theory could explain why water absorbs different gases in different proportions. For example, he found that water absorbs carbon dioxide far better than it absorbs nitrogen.[6] Dalton hypothesized this was due to the differences in mass and complexity of the gases' respective particles. Indeed, carbon dioxide molecules (CO2) are heavier and larger than nitrogen molecules (N2).
In 1827, botanist Robert Brown used a microscope to look at dust grains floating in water and discovered that they moved about erratically, a phenomenon that became known as "Brownian motion". This was thought to be caused by water molecules knocking the grains about. In 1905 Albert Einstein produced the first mathematical analysis of the motion.[7][8][9]French physicist Jean Perrin used Einstein's work to experimentally determine the mass and dimensions of atoms, thereby conclusively verifying Dalton's atomic theory.[10]
The structure of atoms
The physicist J. J. Thomson, through his work on cathode rays in 1897, discovered the electron, and concluded that they were a component of every atom. Thus he overturned the belief that atoms are the indivisible, ultimate particles of matter.[11]Thomson postulated that the low mass, negatively charged electrons were distributed throughout the atom in a uniform sea of positive charge. This became known as the plum pudding model.
In 1909, Hans Geiger and Ernest Marsden, under the direction of Ernest Rutherford, bombarded a metal foil with alpha particles to observe how they scattered. Going by Thomson's plum pudding model, all the alpha particles should have passed straight through the foil with little deflection, because the positive charge of its atoms should have been too dilute to affect them much. They instead observed a small fraction of alpha particles being deflected by angles greater than 90°. To explain this, Rutherford proposed that each atom has a nucleus where the positive charge and most of the mass are concentrated, and these were what were deflecting those alpha particles so strongly.[12]
While experimenting with the products of radioactive decay, in 1913 radiochemistFrederick Soddy discovered that there appeared to be more than one type of atom at each position on the periodic table.[13] The term isotope was coined by Margaret Todd as a suitable name for different atoms that belong to the same element. J.J. Thomson created a technique for separating atom types through his work on ionized gases, which subsequently led to the discovery of stable isotopes.[14]
Meanwhile, in 1913, physicist Niels Bohr suggested that the electrons were confined into clearly defined, quantized orbits, and could jump between these, but could not freely spiral inward or outward in intermediate states like satellites orbiting a planet.[15] An electron must absorb or emit specific amounts of energy to transition between these fixed orbits. This explained why the electrons don't spiral down into the nucleus, and why elements absorb and emit light in discrete spectra.[16]
Later in the same year Henry Moseley provided additional experimental evidence in favor of Niels Bohr's theory. These results refined Ernest Rutherford's and Antonius Van den Broek's model, which proposed that the atom contains in its nucleus a number of positive nuclear charges that is equal to its (atomic) number in the periodic table. Until these experiments, atomic number was not known to be a physical and experimental quantity. That it is equal to the atomic nuclear charge remains the accepted atomic model today.[17]
Chemical bonds between atoms were now explained, by Gilbert Newton Lewis in 1916, as the interactions between their constituent electrons.[18] As the chemical properties of the elements were known to largely repeat themselves according to the periodic law,[19] in 1919 the American chemist Irving Langmuir suggested that this could be explained if the electrons in an atom were connected or clustered in some manner. Groups of electrons were thought to occupy a set of electron shells about the nucleus.[20]
The Stern–Gerlach experiment of 1922 provided further evidence of the quantum nature of the atom. When a beam of silver atoms was passed through a specially shaped magnetic field, the beam was split based on the direction of an atom's angular momentum, or spin. As this direction is random, the beam could be expected to spread into a line. Instead, the beam was split into two parts, depending on whether the atomic spin was oriented up or down.[21]
In 1924, Louis de Broglie proposed that all particles behave to an extent like waves. In 1926, Erwin Schrödinger used this idea to develop a mathematical model of the atom that described the electrons as three-dimensional waveforms rather than point particles. A consequence of using waveforms to describe particles is that it is mathematically impossible to obtain precise values for both the position and momentum of a particle at the same time; this became known as the uncertainty principle, formulated by Werner Heisenberg in 1926. In this concept, for a given accuracy in measuring a position one could only obtain a range of probable values for momentum, and vice versa. This model was able to explain observations of atomic behavior that previous models could not, such as certain structural and spectral patterns of atoms larger than hydrogen. Thus, the planetary model of the atom was discarded in favor of one that described atomic orbital zones around the nucleus where a given electron is most likely to be observed.[22][23]
The development of the mass spectrometer allowed the exact mass of atoms to be measured. The device uses a magnet to bend the trajectory of a beam of ions, and the amount of deflection is determined by the ratio of an atom's mass to its charge. The chemist Francis William Aston used this instrument to show that isotopes had different masses. The atomic mass of these isotopes varied by integer amounts, called the whole number rule.[24] The explanation for these different isotopes awaited the discovery of the neutron, a neutral-charged particle with a mass similar to the proton, by the physicistJames Chadwick in 1932. Isotopes were then explained as elements with the same number of protons, but different numbers of neutrons within the nucleus.[25]
Fission, high-energy physics and condensed matter
In 1938, the German chemist Otto Hahn, a student of Rutherford, directed neutrons onto uranium atoms expecting to gettransuranium elements. Instead, his chemical experiments showed barium as a product.[26] A year later, Lise Meitner and her nephew Otto Frisch verified that Hahn's result were the first experimental nuclear fission.[27][28] In 1944, Hahn received the Nobel prize in chemistry. Despite Hahn's efforts, the contributions of Meitner and Frisch were not recognized.[29]
In the 1950s, the development of improved particle accelerators and particle detectors allowed scientists to study the impacts of atoms moving at high energies.[30] Neutrons and protons were found to be hadrons, or composites of smaller particles called quarks. The standard model of particle physics was developed that so far has successfully explained the properties of the nucleus in terms of these sub-atomic particles and the forces that govern their interactions.[31]
Structure
Subatomic particles
Main article: Subatomic particle
Though the word atom originally denoted a particle that cannot be cut into smaller particles, in modern scientific usage the atom is composed of various subatomic particles. The constituent particles of an atom are the electron, the proton and theneutron; all three are fermions. However, the hydrogen-1 atom has no neutrons and the hydron ion has no electrons.
The electron is by far the least massive of these particles at 9.11×10−31 kg, with a negative electrical charge and a size that is too small to be measured using available techniques.[32] It is the lightest particle with a positive rest mass measured. Under ordinary conditions, electrons are bound to the positively charged nucleus by the attraction created from opposite electric charges. If an atom have more or fewer electrons than its atomic number, then is become respectively negatively or positively charged as a whole; a charged atom is called ion. Electrons are known since the late 19th century, mostly thanks to J.J. Thomson; see history of subatomic physics for details.
Protons have a positive charge and a mass 1,836 times that of the electron, at 1.6726×10−27 kg. The number of protons in an atom is called its atomic number. Ernest Rutherford (1919) observed that nitrogen under alpha-particle bombardment ejects what appeared to be hydrogen nuclei. By 1920 he had accepted that the hydrogen nucleus is a distinct particle within the atom and named it proton.
Neutrons have no electrical charge and have a free mass of 1,839 times the mass of the electron,[33] or 1.6929×10−27 kg, the heaviest of the three constituent particles, but it can be reduced by the nuclear binding energy. Neutrons and protons (collectively known as nucleons) have comparable dimensions—on the order of 2.5×10−15 m—although the 'surface' of these particles is not sharply defined.[34] The neutron was discovered in 1932 by the English physicist James Chadwick.
In the Standard Model of physics, electrons are truly elementary particles with no internal structure. However, both protons and neutrons are composite particles composed of elementary particles called quarks. There are two types of quarks in atoms, each having a fractional electric charge. Protons are composed of two up quarks (each with charge +2⁄3) and onedown quark (with a charge of −1⁄3). Neutrons consist of one up quark and two down quarks. This distinction accounts for the difference in mass and charge between the two particles.[35][36]
The quarks are held together by the strong interaction (or strong force), which is mediated by gluons. The protons and neutrons, in turn, are held to each other in the nucleus by the nuclear force, which is a residuum of the strong force that has somewhat different range-properties (see the article on the nuclear force for more). The gluon is a member of the family ofgauge bosons, which are elementary particles that mediate physical forces.[35][36]
Nucleus
Main article: Atomic nucleus
All the bound protons and neutrons in an atom make up a tinyatomic nucleus, and are collectively called nucleons. The radius of a nucleus is approximately equal to 1.07 3√A fm, where A is the total number of nucleons.[37] This is much smaller than the radius of the atom, which is on the order of 105 fm. The nucleons are bound together by a short-ranged attractive potential called the residual strong force. At distances smaller than 2.5 fm this force is much more powerful than theelectrostatic force that causes positively charged protons to repel each other.[38]
Atoms of the same element have the same number of protons, called the atomic number. Within a single element, the number of neutrons may vary, determining the isotope of that element. The total number of protons and neutrons determine thenuclide. The number of neutrons relative to the protons determines the stability of the nucleus, with certain isotopes undergoing radioactive decay.[39]
The proton, the electron, and the neutron are classified as fermions. Fermions obey the Pauli exclusion principle which prohibits identical fermions, such as multiple protons, from occupying the same quantum state at the same time. Thus, every proton in the nucleus must occupy a quantum state different from all other protons, and the same applies to all neutrons of the nucleus and to all electrons of the electron cloud. However, a proton and a neutron are allowed to occupy the same quantum state.[40]
For atoms with low atomic numbers, a nucleus that has more neutrons than protons tends to drop to a lower energy state through radioactive decay so that the neutron-proton ratio is closer to one. However, as the atomic number increases, a higher proportion of neutrons is required to offset the mutual repulsion of the protons. Thus, there are no stable nuclei with equal proton and neutron numbers above atomic number Z = 20 (calcium) and as Z increases, the neutron-proton ratio of stable isotopes increases.[40] The stable isotope with the highest proton-neutron ration is lead-208 (about 1.5).
The number of protons and neutrons in the atomic nucleus can be modified, although this can require very high energies because of the strong force. Nuclear fusion occurs when multiple atomic particles join to form a heavier nucleus, such as through the energetic collision of two nuclei. For example, at the core of the Sun protons require energies of 3–10 keV to overcome their mutual repulsion—thecoulomb barrier—and fuse together into a single nucleus.[41] Nuclear fission is the opposite process, causing a nucleus to split into two smaller nuclei—usually through radioactive decay. The nucleus can also be modified through bombardment by high energy subatomic particles or photons. If this modifies the number of protons in a nucleus, the atom changes to a different chemical element.[42][43]
If the mass of the nucleus following a fusion reaction is less than the sum of the masses of the separate particles, then the difference between these two values can be emitted as a type of usable energy (such as a gamma ray, or the kinetic energy of a beta particle), as described by Albert Einstein's mass–energy equivalenceformula, E = mc2, where m is the mass loss and c is the speed of light. This deficit is part of the binding energy of the new nucleus, and it is the non-recoverable loss of the energy that causes the fused particles to remain together in a state that requires this energy to separate.[44]
The fusion of two nuclei that create larger nuclei with lower atomic numbers than iron and nickel—a total nucleon number of about 60—is usually an exothermic process that releases more energy than is required to bring them together.[45] It is this energy-releasing process that makes nuclear fusion in stars a self-sustaining reaction. For heavier nuclei, the binding energy per nucleon in the nucleus begins to decrease. That means fusion processes producing nuclei that have atomic numbers higher than about 26, and atomic masses higher than about 60, is an endothermic process. These more massive nuclei can not undergo an energy-producing fusion reaction that can sustain the hydrostatic equilibrium of a star.[40]
Electron cloud
Main articles: Atomic orbital and Electron configuration
The electrons in an atom are attracted to the protons in the nucleus by theelectromagnetic force. This force binds the electrons inside an electrostatic potential well surrounding the smaller nucleus, which means that an external source of energy is needed for the electron to escape. The closer an electron is to the nucleus, the greater the attractive force. Hence electrons bound near the center of the potential well require more energy to escape than those at greater separations.
Electrons, like other particles, have properties of both a particle and a wave. The electron cloud is a region inside the potential well where each electron forms a type of three-dimensional standing wave—a wave form that does not move relative to the nucleus. This behavior is defined by an atomic orbital, a mathematical function that characterises the probability that an electron appears to be at a particular location when its position is measured.[46] Only a discrete (or quantized) set of these orbitals exist around the nucleus, as other possible wave patterns rapidly decay into a more stable form.[47] Orbitals can have one or more ring or node structures, and they differ from each other in size, shape and orientation.[48]
Each atomic orbital corresponds to a particular energy level of the electron. The electron can change its state to a higher energy level by absorbing a photon with sufficient energy to boost it into the new quantum state. Likewise, throughspontaneous emission, an electron in a higher energy state can drop to a lower energy state while radiating the excess energy as a photon. These characteristic energy values, defined by the differences in the energies of the quantum states, are responsible for atomic spectral lines.[47]
The amount of energy needed to remove or add an electron—the electron binding energy—is far less than the binding energy of nucleons. For example, it requires only 13.6 eV to strip a ground-state electron from a hydrogen atom,[49] compared to 2.23 million eV for splitting a deuterium nucleus.[50] Atoms are electrically neutral if they have an equal number of protons and electrons. Atoms that have either a deficit or a surplus of electrons are called ions. Electrons that are farthest from the nucleus may be transferred to other nearby atoms or shared between atoms. By this mechanism, atoms are able to bond into molecules and other types of chemical compounds like ionic and covalent network crystals.[51]
Properties
Nuclear properties
Main articles: Isotope, Stable isotope, List of nuclides and List of elements by stability of isotopes
By definition, any two atoms with an identical number of protons in their nuclei belong to the same chemical element. Atoms with equal numbers of protons but a different number of neutrons are different isotopes of the same element. For example, all hydrogen atoms admit exactly one proton, but isotopes exist with no neutrons (hydrogen-1, by far the most common form,[52] also called protium), one neutron (deuterium), two neutrons (tritium) and more than two neutrons. The known elements form a set of atomic numbers, from the single proton element hydrogen up to the 118-proton elementununoctium.[53] All known isotopes of elements with atomic numbers greater than 82 are radioactive.[54][55]
About 339 nuclides occur naturally on Earth,[56] of which 254 (about 75%) have not been observed to decay, and are referred to as "stable isotopes". However, only 90 of these nuclides are stable to all decay, even in theory. Another 164 (bringing the total to 254) have not been observed to decay, even though in theory it is energetically possible. These are also formally classified as "stable". An additional 34 radioactive nuclides have half-lives longer than 80 million years, and are long-lived enough to be present from the birth of the solar system. This collection of 288 nuclides are known as primordial nuclides. Finally, an additional 51 short-lived nuclides are known to occur naturally, as daughter products of primordial nuclide decay (such as radium from uranium), or else as products of natural energetic processes on Earth, such as cosmic ray bombardment (for example, carbon-14).[57][note 2]
For 80 of the chemical elements, at least one stable isotope exists. As a rule, there is only a handful of stable isotopes for each of these elements, the average being 3.2 stable isotopes per element. Twenty-six elements have only a single stable isotope, while the largest number of stable isotopes observed for any element is ten, for the element tin. Elements 43, 61, and all elements numbered 83 or higher have no stable isotopes.[58][page needed]
Stability of isotopes is affected by the ratio of protons to neutrons, and also by the presence of certain "magic numbers" of neutrons or protons that represent closed and filled quantum shells. These quantum shells correspond to a set of energy levels within the shell model of the nucleus; filled shells, such as the filled shell of 50 protons for tin, confers unusual stability on the nuclide. Of the 254 known stable nuclides, only four have both an odd number of protons and odd number of neutrons: hydrogen-2 (deuterium), lithium-6, boron-10 and nitrogen-14. Also, only four naturally occurring, radioactive odd-odd nuclides have a half-life over a billion years: potassium-40, vanadium-50, lanthanum-138 and tantalum-180m. Most odd-odd nuclei are highly unstable with respect to beta decay, because the decay products are even-even, and are therefore more strongly bound, due to nuclear pairing effects.[58][page needed]
Mass
Main articles: Atomic mass and mass number
The large majority of an atom's mass comes from the protons and neutrons that make it up. The total number of these particles (called "nucleons") in a given atom is called the mass number. The mass number is a simple whole number, and has units of "nucleons." An example of use of a mass number is "carbon-12," which has 12 nucleons (six protons and six neutrons).
The actual mass of an atom at rest is often expressed using the unified atomic mass unit (u), which is also called a dalton (Da). This unit is defined as a twelfth of the mass of a free neutral atom of carbon-12, which is approximately1.66×10−27 kg.[59] Hydrogen-1, the lightest isotope of hydrogen and the atom with the lowest mass, has an atomic weight of 1.007825 u.[60] The value of this number is called the atomic mass. A given atom has an atomic mass approximately equal (within 1%) to its mass number times the mass of the atomic mass unit. However, this number will not be an exact whole number except in the case of carbon-12 (see below).[61] The heaviest stable atom is lead-208,[54] with a mass of207.9766521 u.[62]
As even the most massive atoms are far too light to work with directly, chemists instead use the unit of moles. One mole of atoms of any element always has the same number of atoms (about 6.022×1023). This number was chosen so that if an element has an atomic mass of 1 u, a mole of atoms of that element has a mass close to one gram. Because of the definition of the unified atomic mass unit, each carbon-12 atom has an atomic mass of exactly 12 u, and so a mole of carbon-12 atoms weighs exactly 0.012 kg.[59][page needed]
Shape and size
Main article: Atomic radius
Atoms lack a well-defined outer boundary, so their dimensions are usually described in terms of an atomic radius. This is a measure of the distance out to which the electron cloud extends from the nucleus.[citation needed] However, this assumes the atom to exhibit a spherical shape, which is only obeyed for atoms in vacuum or free space. Atomic radii may be derived from the distances between two nuclei when the two atoms are joined in a chemical bond. The radius varies with the location of an atom on the atomic chart, the type of chemical bond, the number of neighboring atoms (coordination number) and aquantum mechanical property known as spin.[63] On the periodic table of the elements, atom size tends to increase when moving down columns, but decrease when moving across rows (left to right).[64] Consequently, the smallest atom is helium with a radius of 32 pm, while one of the largest is caesium at 225 pm.[65]
When subjected to external fields, like an electrical field, the shape of an atom may deviate from spherical symmetry. The deformation depends on the field magnitude and the orbital type of outer shell electrons, as shown by group-theoreticalconsiderations. Aspherical deviations might be elicited for instance in crystals, where large crystal-electrical fields may occur at low-symmetry lattice sites.[66] Significant ellipsoidal deformations have recently been shown to occur for sulfur ions inpyrite-type compounds.[67]
Atomic dimensions are thousands of times smaller than the wavelengths of light (400–700 nm) so they can not be viewed using an optical microscope. However, individual atoms can be observed using a scanning tunneling microscope. To visualize the minuteness of the atom, consider that a typical human hair is about 1 million carbon atoms in width.[68] A single drop of water contains about 2 sextillion (2×1021) atoms of oxygen, and twice the number of hydrogen atoms.[69] A singlecarat diamond with a mass of 2×10−4 kg contains about 10 sextillion (1022) atoms of carbon.[note 3] If an apple were magnified to the size of the Earth, then the atoms in the apple would be approximately the size of the original apple.[70]
Radioactive decay
Main article: Radioactive decay
Every element has one or more isotopes that have unstable nuclei that are subject to radioactive decay, causing the nucleus to emit particles or electromagnetic radiation. Radioactivity can occur when the radius of a nucleus is large compared with the radius of the strong force, which only acts over distances on the order of 1 fm.[71]
- Alpha decay: this process is caused when the nucleus emits an alpha particle, which is a helium nucleus consisting of two protons and two neutrons. The result of the emission is a new element with a lower atomic number.
- Beta decay (and electron capture): these processes are regulated by the weak force, and result from a transformation of a neutron into a proton, or a proton into a neutron. The neutron to proton transition is accompanied by the emission of an electron and anantineutrino, while proton to neutron transition (except in electron capture) causes the emission of a positron and a neutrino. The electron or positron emissions are called beta particles. Beta decay either increases or decreases the atomic number of the nucleus by one. Electron capture is more common than positron emission, because it requires less energy. In this type of decay, an electron is absorbed by the nucleus, rather than a positron emitted from the nucleus. A neutrino is still emitted in this process, and a proton changes to a neutron.
- Gamma decay: this process results from a change in the energy level of the nucleus to a lower state, resulting in the emission of electromagnetic radiation. The excited state of a nucleus which results in gamma emission usually occurs following the emission of an alpha or a beta particle. Thus, gamma decay usually follows alpha or beta decay.
Other more rare types of radioactive decay include ejection of neutrons or protons or clusters of nucleons from a nucleus, or more than one beta particle. An analog of gamma emission which allows excited nuclei to lose energy in a different way, isinternal conversion— a process that produces high-speed electrons that are not beta rays, followed by production of high-energy photons that are not gamma rays. A few large nuclei explode into two or more charged fragments of varying masses plus several neutrons, in a decay called spontaneous nuclear fission.
Each radioactive isotope has a characteristic decay time period—the half-life—that is determined by the amount of time needed for half of a sample to decay. This is an exponential decay process that steadily decreases the proportion of the remaining isotope by 50% every half-life. Hence after two half-lives have passed only 25% of the isotope is present, and so forth.[71]
Magnetic moment
Main articles: Electron magnetic dipole moment and Nuclear magnetic moment
Elementary particles possess an intrinsic quantum mechanical property known as spin. This is analogous to the angular momentum of an object that is spinning around its center of mass, although strictly speaking these particles are believed to be point-like and cannot be said to be rotating. Spin is measured in units of the reduced Planck constant (ħ), with electrons, protons and neutrons all having spin ½ ħ, or "spin-½". In an atom, electrons in motion around the nucleus possess orbitalangular momentum in addition to their spin, while the nucleus itself possesses angular momentum due to its nuclear spin.[74]
The magnetic field produced by an atom—its magnetic moment—is determined by these various forms of angular momentum, just as a rotating charged object classically produces a magnetic field. However, the most dominant contribution comes from spin. Due to the nature of electrons to obey the Pauli exclusion principle, in which no two electrons may be found in the same quantum state, bound electrons pair up with each other, with one member of each pair in a spin up state and the other in the opposite, spin down state. Thus these spins cancel each other out, reducing the total magnetic dipole moment to zero in some atoms with even number of electrons.[75]
In ferromagnetic elements such as iron, an odd number of electrons leads to an unpaired electron and a net overall magnetic moment. The orbitals of neighboring atoms overlap and a lower energy state is achieved when the spins of unpaired electrons are aligned with each other, a process known as an exchange interaction. When the magnetic moments of ferromagnetic atoms are lined up, the material can produce a measurable macroscopic field. Paramagnetic materialshave atoms with magnetic moments that line up in random directions when no magnetic field is present, but the magnetic moments of the individual atoms line up in the presence of a field.[75][76]
The nucleus of an atom can also have a net spin. Normally these nuclei are aligned in random directions because of thermal equilibrium. However, for certain elements (such as xenon-129) it is possible to polarize a significant proportion of the nuclear spin states so that they are aligned in the same direction—a condition called hyperpolarization. This has important applications in magnetic resonance imaging.[77][78]
Energy levels
The potential energy of an electron in an atom is negative, its dependence of itsposition reaches the minimum (the most absolute value) inside the nucleus, and vanishes when the distance from the nucleus goes to infinity, roughly in an inverse proportion to the distance. In the quantum-mechanical model, a bound electron can only occupy a set of states centered on the nucleus, and each state corresponds to a specific energy level; see time-independent Schrödinger equation for theoretical explanation. An energy level can be measured by the amount of energy needed to unbind the electron from the atom, and is usually given in units of electronvolts (eV). The lowest energy state of a bound electron is called the ground state, i.e.stationary state, while an electron transition to a higher level results in an excited state.[79] The electron's energy raises when n increases because the (average) distance to the nucleus increases. Dependence of the energy on ℓ is caused not byelectrostatic potential of the nucleus, but by interaction between electrons.
For an electron to transition between two different states, e.g. grounded state to first excited level (ionization), it must absorb or emit a photon at an energy matching the difference in the potential energy of those levels, according to Niels Bohr model, what can be precisely calculated by the Schrödinger equation. Electrons jump between orbitals in a particle-like fashion. For example, if a single photon strikes the electrons, only a single electron changes states in response to the photon; seeElectron properties.
The energy of an emitted photon is proportional to its frequency, so these specific energy levels appear as distinct bands in the electromagnetic spectrum.[80] Each element has a characteristic spectrum that can depend on the nuclear charge, subshells filled by electrons, the electromagnetic interactions between the electrons and other factors.[81]
When a continuous spectrum of energy is passed through a gas orplasma, some of the photons are absorbed by atoms, causing electrons to change their energy level. Those excited electrons that remain bound to their atom spontaneously emit this energy as a photon, traveling in a random direction, and so drop back to lower energy levels. Thus the atoms behave like a filter that forms a series of darkabsorption bands in the energy output. (An observer viewing the atoms from a view that does not include the continuous spectrum in the background, instead sees a series of emission lines from the photons emitted by the atoms.) Spectroscopic measurements of the strength and width of atomic spectral lines allow the composition and physical properties of a substance to be determined.[82]
Close examination of the spectral lines reveals that some display a fine structure splitting. This occurs because of spin–orbit coupling, which is an interaction between the spin and motion of the outermost electron.[83] When an atom is in an external magnetic field, spectral lines become split into three or more components; a phenomenon called the Zeeman effect. This is caused by the interaction of the magnetic field with the magnetic moment of the atom and its electrons. Some atoms can have multiple electron configurations with the same energy level, which thus appear as a single spectral line. The interaction of the magnetic field with the atom shifts these electron configurations to slightly different energy levels, resulting in multiple spectral lines.[84] The presence of an external electric field can cause a comparable splitting and shifting of spectral lines by modifying the electron energy levels, a phenomenon called the Stark effect.[85]
If a bound electron is in an excited state, an interacting photon with the proper energy can cause stimulated emission of a photon with a matching energy level. For this to occur, the electron must drop to a lower energy state that has an energy difference matching the energy of the interacting photon. The emitted photon and the interacting photon then move off in parallel and with matching phases. That is, the wave patterns of the two photons are synchronized. This physical property is used to make lasers, which can emit a coherent beam of light energy in a narrow frequency band.[86]
Valence and bonding behavior
Main articles: Valence (chemistry) and Chemical bond
The outermost electron shell of an atom in its uncombined state is known as the valence shell, and the electrons in that shell are called valence electrons. The number of valence electrons determines the bonding behavior with other atoms. Atoms tend to chemically react with each other in a manner that fills (or empties) their outer valence shells.[87] For example, a transfer of a single electron between atoms is a useful approximation for bonds that form between atoms with one-electron more than a filled shell, and others that are one-electron short of a full shell, such as occurs in the compound sodium chloride and other chemical ionic salts. However, many elements display multiple valences, or tendencies to share differing numbers of electrons in different compounds. Thus, chemical bonding between these elements takes many forms of electron-sharing that are more than simple electron transfers. Examples include the element carbon and the organic compounds.[88]
The chemical elements are often displayed in a periodic table that is laid out to display recurring chemical properties, and elements with the same number of valence electrons form a group that is aligned in the same column of the table. (The horizontal rows correspond to the filling of a quantum shell of electrons.) The elements at the far right of the table have their outer shell completely filled with electrons, which results in chemically inert elements known as the noble gases.[89][90]
States
Main articles: State of matter and Phase (matter)
Quantities of atoms are found in different states of matter that depend on the physical conditions, such as temperature and pressure. By varying the conditions, materials can transition between solids, liquids, gases and plasmas. [91] Within a state, a material can also exist in different allotropes. An example of this is solid carbon, which can exist as graphite or diamond.[92] Gaseous allotropes exist as well, such as dioxygen and ozone.
At temperatures close to absolute zero, atoms can form a Bose–Einstein condensate, at which point quantum mechanical effects, which are normally only observed at the atomic scale, become apparent on a macroscopic scale.[93][94] This super-cooled collection of atoms then behaves as a single super atom, which may allow fundamental checks of quantum mechanical behavior.[95]
Identification
The scanning tunneling microscope is a device for viewing surfaces at the atomic level. It uses the quantum tunneling phenomenon, which allows particles to pass through a barrier that would normally be insurmountable. Electrons tunnel through the vacuum between two planar metal electrodes, on each of which is an adsorbedatom, providing a tunneling-current density that can be measured. Scanning one atom (taken as the tip) as it moves past the other (the sample) permits plotting of tip displacement versus lateral separation for a constant current. The calculation shows the extent to which scanning-tunneling-microscope images of an individual atom are visible. It confirms that for low bias, the microscope images the space-averaged dimensions of the electron orbitals across closely packed energy levels—the Fermi level local density of states.[96][97]
An atom can be ionized by removing one of its electrons. The electric charge causes the trajectory of an atom to bend when it passes through a magnetic field. The radius by which the trajectory of a moving ion is turned by the magnetic field is determined by the mass of the atom. The mass spectrometer uses this principle to measure the mass-to-charge ratio of ions. If a sample contains multiple isotopes, the mass spectrometer can determine the proportion of each isotope in the sample by measuring the intensity of the different beams of ions. Techniques to vaporize atoms include inductively coupled plasma atomic emission spectroscopy and inductively coupled plasma mass spectrometry, both of which use a plasma to vaporize samples for analysis.[98]
A more area-selective method is electron energy loss spectroscopy, which measures the energy loss of an electron beamwithin a transmission electron microscope when it interacts with a portion of a sample. The atom-probe tomograph has sub-nanometer resolution in 3-D and can chemically identify individual atoms using time-of-flight mass spectrometry.[99]
Spectra of excited states can be used to analyze the atomic composition of distant stars. Specific light wavelengthscontained in the observed light from stars can be separated out and related to the quantized transitions in free gas atoms. These colors can be replicated using a gas-discharge lamp containing the same element.[100] Helium was discovered in this way in the spectrum of the Sun 23 years before it was found on Earth.[101]
Origin and current state
Atoms form about 4% of the total energy density of the observable Universe, with an average density of about 0.25 atoms/m3.[102] Within a galaxy such as the Milky Way, atoms have a much higher concentration, with the density of matter in the interstellar medium (ISM) ranging from 105 to 109 atoms/m3.[103] The Sun is believed to be inside the Local Bubble, a region of highly ionized gas, so the density in the solar neighborhood is only about 103 atoms/m3.[104] Stars form from dense clouds in the ISM, and the evolutionary processes of stars result in the steady enrichment of the ISM with elements more massive than hydrogen and helium. Up to 95% of the Milky Way's atoms are concentrated inside stars and the total mass of atoms forms about 10% of the mass of the galaxy.[105] (The remainder of the mass is an unknown dark matter.)[106]
Formation
Electrons are thought to exist in the Universe since early stages of the Big Bang. Atomic nuclei forms in nucleosynthesisreactions. In about three minutes Big Bang nucleosynthesis produced most of the helium, lithium, and deuterium in the Universe, and perhaps some of the beryllium and boron.[107][108][109]
Ubiquitousness and stability of atoms relies on their binding energy, which means that an atom has a lower energy than an unbound system of the nucleus and electrons. Where the temperature is much higher than ionization potential, the matter exists in the form of plasma – a gas of positively-charged ions (possibly, bare nuclei) and electrons. When the temperature drops below the ionization potential, atoms become statistically favorable. Atoms (complete with bound electrons) became to dominate over charged particles 380,000 years after the Big Bang—an epoch called recombination, when the expanding Universe cooled enough to allow electrons to become attached to nuclei.[110]
Since the Big Bang, which produced no carbon or heavier elements, atomic nuclei have been combined in stars through the process of nuclear fusion to produce more of the element helium, and (via the triple alpha process) the sequence of elements from carbon up to iron;[111] see stellar nucleosynthesis for details.
Isotopes such as lithium-6, as well as some beryllium and boron are generated in space through cosmic ray spallation.[112]This occurs when a high-energy proton strikes an atomic nucleus, causing large numbers of nucleons to be ejected.
Elements heavier than iron were produced in supernovae through the r-process and in AGB stars through the s-process, both of which involve the capture of neutrons by atomic nuclei.[113] Elements such as lead formed largely through the radioactive decay of heavier elements.[114]
Earth
Most of the atoms that make up the Earth and its inhabitants were present in their current form in the nebula that collapsed out of a molecular cloud to form the Solar System. The rest are the result of radioactive decay, and their relative proportion can be used to determine the age of the Earth through radiometric dating.[115][116] Most of the helium in the crust of the Earth (about 99% of the helium from gas wells, as shown by its lower abundance of helium-3) is a product of alpha decay.[117]
There are a few trace atoms on Earth that were not present at the beginning (i.e., not "primordial"), nor are results of radioactive decay. Carbon-14 is continuously generated by cosmic rays in the atmosphere.[118] Some atoms on Earth have been artificially generated either deliberately or as by-products of nuclear reactors or explosions.[119][120] Of the transuranic elements—those with atomic numbers greater than 92—only plutonium and neptunium occur naturally on Earth.[121][122]Transuranic elements have radioactive lifetimes shorter than the current age of the Earth[123] and thus identifiable quantities of these elements have long since decayed, with the exception of traces of plutonium-244 possibly deposited by cosmic dust.[124] Natural deposits of plutonium and neptunium are produced by neutron capture in uranium ore.[125]
The Earth contains approximately 1.33×1050 atoms.[126] Although small numbers of independent atoms of noble gasesexist, such as argon, neon, and helium, 99% of the atmosphere is bound in the form of molecules, including carbon dioxideand diatomic oxygen and nitrogen. At the surface of the Earth, an overwhelming majority of atoms combine to form various compounds, including water, salt, silicates and oxides. Atoms can also combine to create materials that do not consist of discrete molecules, including crystals and liquid or solid metals.[127][128] This atomic matter forms networked arrangements that lack the particular type of small-scale interrupted order associated with molecular matter.[129]
Rare and theoretical forms
Superheavy elements
Main article: Transuranium element
While isotopes with atomic numbers higher than lead (82) are known to be radioactive, an "island of stability" has been proposed for some elements with atomic numbers above 103. These superheavy elements may have a nucleus that is relatively stable against radioactive decay.[130] The most likely candidate for a stable superheavy atom, unbihexium, has 126 protons and 184 neutrons.[131]
Exotic matter
Main article: Exotic matter
Each particle of matter has a corresponding antimatter particle with the opposite electrical charge. Thus, the positron is a positively charged antielectron and the antiproton is a negatively charged equivalent of a proton. When a matter and corresponding antimatter particle meet, they annihilate each other. Because of this, along with an imbalance between the number of matter and antimatter particles, the latter are rare in the universe. The first causes of this imbalance are not yet fully understood, although theories of baryogenesis may offer an explanation. As a result, no antimatter atoms have been discovered in nature.[132][133] However, in 1996 the antimatter counterpart of the hydrogen atom (antihydrogen) was synthesized at the CERN laboratory in Geneva.[134][135]
Other exotic atoms have been created by replacing one of the protons, neutrons or electrons with other particles that have the same charge. For example, an electron can be replaced by a more massive muon, forming a muonic atom. These types of atoms can be used to test the fundamental predictions of physics.[136][137][138]
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